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Risk Pharses(R) Combination Riskphrases Safety Pharses(S) Combination Hazardous
   
 

    Risk Pharses (R)  
R 1 Explosive When dry.
R 2 Risk of explosion by shock, friction, fire or other sources of ignition.
R 3 Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R 4 Forms very sensitive explosive metallic compounds.
R 5 Heating may cause an explosion.
R 6 Explosive with or without contact with air.
R 7 May cause fire.
R 8 Contact with combustible material may cause fire.
R 9 Explosive when mixed with combustible material.
R 10 Flammable.
R 11 Highly flammable.
R 12 Extremely flammable.
R 13 Extremely flammable liquified gas.
R 14 Reacts violently with water.
R 15 Contact with water liberates highly flammable gases.
R 16 Explosive when mixed with oxidizing substances.
R 17 Spontaneously flammable in air.
R 18 In use, may from flammable/explosive vapour-air mixture.
R 19 May form explosive peroxides.
R 20 Harmful by inhalation.
R 21 Harmful in contact with skin
R 22 Harmful if swallowed.
R 23 Toxic by inhalation.
R 24 Toxic in contact with skin.
R 25 Toxic if swallowed.
R 26 Very toxic by inhalation.
R 27 Very toxic in contact with skin.
R 28 Very toxic if swallowed.
R 29 Contact with water liberates toxic gas.
R 30 Can become highly flammable in use.
R 31 Contact with acids
R 32 Contact with acids liberates very toxic gas.
R 33 Danger of cumulative effects.
R 34 Causes burns
R 35 Causes severe burns.
R 36 Irritating to eyes.
R 37 Irritating to respiratory system.
R 38 Irritating to skin.
R 39 Danger of very serious irreversible effects.
R 40 Possible risk of irreversible effects.
R 41 Risk of serious damage to eyes.
R 42 May cause sensitization by inhalation.
R 43 May cause sensitization by skin contact.
R 44 Risk of explosion if heated under confinement.
R 45 May cause cancer.
R 46 May cause heritable genetic damage.
R 47 May cause birth defects.
R 48 Danger of serious damage to health by prolonged exposure.
R 49 May cause cancer by inhalation.
R 50 Very toxic to aquatic organisms.
R 51 Toxic to aquatic organisms.
R 52 Harmful to aquatic organisms.
R 53 May cause long-term adverse effects in the aquatic environment.
R 54 Toxic to flora.
R 55 Toxic to fauna.
R 56 Toxic to soil organisms.
R 57 Toxic to bees.
R 58 May cause long-term adverse in the environment.
R 59 Dangerous for the ozone layer
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    Combination Riskphrases  
R 14/15 Reacts violently with water liberating highly flammable gases.
R 15/29 Contact with water liberates toxic, highly flammable gas.
R 20/21 Harmful by inhalation and in contact with skin.
R 20/22 Harmful by inhalation and if swallowed.
R 21/22 Harmful in contact with skin and if swallowed.
R 20/21/22 Harmful by inhalation, in contact with skin if swallowed.
R 23/24 Toxic by inhalation and in contact with skin.
R 23/25 Toxic by inhalation and if swallowed.
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R 24/25 Toxic in contact with skin and if swallowed.
R 26/27 Very toxic by inhalation and in contact with skin.
R 26/28 Very toxic by inhalation and if swallowed.
R 26/27/28 Very toxic by inhalation, in contact with skin and if swallowed.
R 27/28 Very toxic in contact with skin and if swallowed.
R 36/37 Irritating to eyes and respiratory system.
R 36/38 Irritating to eyes and skin
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 37/38 Irritating to respiratory system and skin.
R 39/23 Toxic : danger of very serious irreversible effects through inhalation.
R 39/24 Toxic : danger of very serious irreversible effects in contact with skin.
R 39/25 Toxic : danger of very serious irreversible effects if swallowed.
R 39/23/24 Toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
R 39/23/25 Toxic : danger of very serious irreversible effects through inhalation and if swallowed.
R 39/24/25 Toxic : danger or very serious irreversible effects in contact with skin and if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible effect through inhalation, in contact with skin and if swallowed.
R 39/26 Very toxic : danger of very serious irreversible effects through inhalation.
R 39/27 Very toxic : danger of very serious irreversible effects in contact with skin.
R 39/28 Very toxic : danger of very serious irreversible effects if swallowed.
R 39/26/27 Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
R 39/26/28 Very toxic : danger of very serious irreversible effects through inhalation and if swallowed
R 39/27/28 Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
R 39/26/27/28 Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
R 40/20 Harmful : possible risk of irreversible effects through inhalation.
R 40/21 Harmful : possible risk of irreversible effects in contact with skin.
R 40/22 Harmful : possible risk of irreversible effects if swallowed.
R 40/20/21 Harmful : possible risk of irreversible effects through inhalation and in contact with skin.
R 40/21/22 Harmful : possible risk of irreversible effects in contact with skin and if swallowed.
R 40/20/21/22 Harmful : possible risk of irreversible effects through inhalation in contact with skin and if swallowed.
R 42/43 May cause sensitization by inhalation and skin contact.
R 48/20 Harmful : danger of serious damage to health by prolonged exposure through inhalation.
R 48/21 Harmful : danger of serious damage to health by prolonged exposure in contact with skin.
R 48/22 Harmful : danger of serious damage to health by prolonged exposure if swallowed
R 48/20/21 Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R 48/20/22 Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R 48/21/22 Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R 48/20/21/22 Harmful : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R 48/23 Toxic : danger of serious damage to health by prolonged exposure through inhalation.
R 48/24 Toxic : danger of serious damage to health by prolonged exposure in contact with skin
R 48/25 Toxic : danger of serious damage to health by prolonged exposure if swallowed.
R 48/23/24 Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R 48/23/25 Toxic : danger of serious damage to health by prolonged exposure through inhalation & of swallowed.
R 4824/25 Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R 48/23/24/25 Toxic : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.


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    Safety Pharses (S)  
S 1 Keep locked up
S 2 Keep out of reach of children.
S 3 Keep in cool place.
S 4 Keep away from living quarters.
S 5 Keep contents under.. (appropriate liquid to be specified by the manufacturer)
S 6 Keep under ... (inert gas to be specified by the manufacturer)
S 7 Keep container tightly closed.
S 8 Keep container dry.
S 9 Keep container in a well ventilated place.
S 12 Do not keep the container sealed.
S 13 Keep away from food, drink and animal feeding stuffs.
S 14 Keep away from... (incompetable materials to be indicated by the manufacturer)
S 15 Keep away from heat.
S 16 Keep away from sources of ignition No smoking.
S 17 Keep away from combustible material.
S 18 Handle and open container with care.
S 20 When using do not eat or drink.
S 21 When using do not smoking.
S 22 Do not breathe dust.
S 23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
S 24 Avoid contact with skin.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28 After contact with skin, wash immediately with plenty of..(to be specified by the manufacturer)
S 29 Do not empty into drains.
S 30 Never add water to this product.
S 33 Take precautionary measures against static discharges.
S 34 Avoid shock and friction.
S 35 This material and its container must be disposed of in a safe way.
S 36 Wear suitable protective clothing.
S 37 Wear suitable gloves.
S 38 In case of insufficient Ventilation wear suitable respiratory equipment.
S 39 Wear eye/face protection.
S 40 To clean the floor and all objects contaminated by this material use... (to be specified by the manufacturer).
S 41 In case of fire and/or explosion do not breathe fumes.
S 42 During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified).
S 43 In case of fire, use..(indicated in the space the precise type of fire fighting equipment. If water increases the risk, add-never use water).
S 44 If you feel unwell, seek, medical advice (show the label where possible).
S 45 In case of accident or if you feel unwell., seek medical advice immediately (show the label where possible)
S 46 If swallowed seek medical advice immediately and show this container or label
S 47 Keep at temperature no exceeding.. C (to be specified by the manufacturer)
S 48 Keep wetted with ... (appropriate material to be specified by the manufacturer)
S 49 Keep only in the original container.
S 50 Do not mix with .. (to be a specified by the manufacturer).
S 51 Use only in well ventilated areas.
S 52 Not recommended for interior use on large surface areas.
S 53 Avoid exposure - obtain special instructions before use instruction.
S 54 Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.
S 55 Treat using the best available techniques before discharge into drains or the aquatic environment.
S 56 Do not discharge into drains or the environment, dispose to an authorised waste collection point.
S 57 Use appropriate containment to avoid environmental contamination.
S 58 To be disposed of as hazardous waste.
S 59 Refer to manufacturer/supplier for information on recovery/recycling.
S 60 This material and/or its container must be disposed of as hazardous waste.
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    Combination Safety Phrases  
S
1/2
Keep locked up and out of reach of children.
S
3/7/9
Keep container tightly closed in a cool well-ventillated place.
S
3/9
Keep in a cool well-ventilated pace.
S
3/9/14
Keep in a cool, well-ventilated place away from ... (incompatible material to be indicated by the manufacturer)
S
3/914/49
Keep only in the original container in a cool wellventilated place away from ... (incompatible materials to be indicated by the manufacturer).
S
3/9/49
Keep only in the original container in a cool wellventilated place.
S
3/14
Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer).
S
7/8
Keep container tightly closed and dry.
S
7/9
Keep container tightly closed and in well-ventilated place.
S
20/21
When using do not eat, drink or smoke.
S
24/25
Avoid contact with skin and eyes.
S
36/37
Wear suitable protective clothing and gloves.
S
36/39
Wear suitable protective clothing and eye/face protection.
S
37/39
Wear suitable gloves and eye/face protection.
S
36/37/39
Wear suitable protective clothing, gloves and eye/face pro
S
47/49
Keep only in the original container at temperature not exceeding .. C (to be specified by the manufacturer).
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F 1 Sensitive to air and humidity.
  2 Sensitive air and CO
  3 Hygroscopic
  4 Do not heat over ... C
  5 Dry material may explode.
  6 Reacts with acids.