Safety Details

R1Explosive When dry.
R2Risk of explosion by shock, friction, fire or other sources of ignition.
R3Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R4Forms very sensitive explosive metallic compounds.
R5Heating may cause an explosion.
R6Explosive with or without contact with air.
R7May cause fire.
R8Contact with combustible material may cause fire.
R9Explosive when mixed with combustible material.
R10Flammable.
R11Highly flammable.
R12Extremely flammable.
R13Extremely flammable liquified gas.
R14Reacts violently with water.
R15Contact with water liberates highly flammable gases.
R16Explosive when mixed with oxidizing substances.
R17Spontaneously flammable in air.
R18In use, may from flammable/explosive vapour-air mixture.
R19May form explosive peroxides.
R20Harmful by inhalation.
R21Harmful in contact with skin
R22Harmful if swallowed.
R23Toxic by inhalation.
R24Toxic in contact with skin.
R25Toxic if swallowed.
R26Very toxic by inhalation.
R27Very toxic in contact with skin.
R28Very toxic if swallowed.
R29Contact with water liberates toxic gas.
R30Can become highly flammable in use.
R31Contact with acids
R32Contact with acids liberates very toxic gas.
R33Danger of cumulative effects.
R34Causes burns
R35Causes severe burns.
R36Irritating to eyes.
R37Irritating to respiratory system.
R38Irritating to skin.
R39Danger of very serious irreversible effects.
R40Possible risk of irreversible effects.
R41Risk of serious damage to eyes.
R42May cause sensitization by inhalation.
R43May cause sensitization by skin contact.
R44Risk of explosion if heated under confinement.
R45May cause cancer.
R46May cause heritable genetic damage.
R47May cause birth defects.
R48Danger of serious damage to health by prolonged exposure.
R49May cause cancer by inhalation.
R50Very toxic to aquatic organisms.
R51Toxic to aquatic organisms.
R52Harmful to aquatic organisms.
R53May cause long-term adverse effects in the aquatic environment.
R54Toxic to flora.
R55Toxic to fauna.
R56Toxic to soil organisms.
R57Toxic to bees.
R58May cause long-term adverse in the environment.
R59Dangerous for the ozone layer
R14/15Reacts violently with water liberating highly flammable gases.
R15/29Contact with water liberates toxic, highly flammable gas.
R20/21Harmful by inhalation and in contact with skin.
R20/22Harmful by inhalation and if swallowed.
R21/22Harmful in contact with skin and if swallowed.
R20/21/22Harmful by inhalation, in contact with skin if swallowed.
R23/24Toxic by inhalation and in contact with skin.
R23/25Toxic by inhalation and if swallowed.
R23/24/25Toxic by inhalation, in contact with skin and if swallowed
R24/25Toxic in contact with skin and if swallowed.
R26/27Very toxic by inhalation and in contact with skin.
R26/28Very toxic by inhalation and if swallowed.
R26/27/28Very toxic by inhalation, in contact with skin and if swallowed.
R27/28Very toxic in contact with skin and if swallowed.
R36/37Irritating to eyes and respiratory system.
R36/38Irritating to eyes and skin
R36/37/38Irritating to eyes, respiratory system and skin.
R37/38Irritating to respiratory system and skin.
R39/23Toxic : danger of very serious irreversible effects through inhalation.
R39/24Toxic : danger of very serious irreversible effects in contact with skin.
R39/25Toxic : danger of very serious irreversible effects if swallowed.
R39/23/24Toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
R39/23/25Toxic : danger of very serious irreversible effects through inhalation and if swallowed.
R39/24/25Toxic : danger or very serious irreversible effects in contact with skin and if swallowed.
R39/23/24/25Toxic : danger of very serious irreversible effect through inhalation, in contact with skin and if swallowed.
R39/26Very toxic : danger of very serious irreversible effects through inhalation.
R39/27Very toxic : danger of very serious irreversible effects in contact with skin.
R39/28Very toxic : danger of very serious irreversible effects if swallowed.
R39/26/27Very toxic : danger of very serious irreversible effects through inhalation and in contact with skin.
R39/26/28Very toxic : danger of very serious irreversible effects through inhalation and if swallowed
R39/27/28Very toxic : danger of very serious irreversible effects in contact with skin and if swallowed.
R39/26/27/28Very toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
R40/20Harmful : possible risk of irreversible effects through inhalation.
R40/21Harmful : possible risk of irreversible effects in contact with skin.
R40/22Harmful : possible risk of irreversible effects if swallowed.
R40/20/21Harmful : possible risk of irreversible effects through inhalation and in contact with skin.
R40/21/22Harmful : possible risk of irreversible effects in contact with skin and if swallowed.
R40/20/21/22Harmful : possible risk of irreversible effects through inhalation in contact with skin and if swallowed.
R42/43May cause sensitization by inhalation and skin contact.
R48/20Harmful : danger of serious damage to health by prolonged exposure through inhalation.
R48/21Harmful : danger of serious damage to health by prolonged exposure in contact with skin.
R48/22Harmful : danger of serious damage to health by prolonged exposure if swallowed
R48/20/21Harmful : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R48/20/22Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R48/21/22Harmful : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R48/20/21/22Harmful : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R48/23Toxic : danger of serious damage to health by prolonged exposure through inhalation.
R48/24Toxic : danger of serious damage to health by prolonged exposure in contact with skin
R48/25Toxic : danger of serious damage to health by prolonged exposure if swallowed.
R48/23/24Toxic : danger of serious damage to health by prolonged exposure through inhalation and in contact with skin.
R48/23/25Toxic : danger of serious damage to health by prolonged exposure through inhalation & of swallowed.
R4824/25Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R48/23/24/25Toxic : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
S1Keep locked up
S2Keep out of reach of children.
S3Keep in cool place.
S4Keep away from living quarters.
S5Keep contents under.. (appropriate liquid to be specified by the manufacturer)
S6Keep under ... (inert gas to be specified by the manufacturer)
S7Keep container tightly closed.
S8Keep container dry.
S9Keep container in a well ventilated place.
S12Do not keep the container sealed.
S13Keep away from food, drink and animal feeding stuffs.
S14Keep away from... (incompetable materials to be indicated by the manufacturer)
S15Keep away from heat.
S16Keep away from sources of ignition No smoking.
S17Keep away from combustible material.
S18Handle and open container with care.
S20When using do not eat or drink.
S21When using do not smoking.
S22Do not breathe dust.
S23Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
S24Avoid contact with skin.
S25Avoid contact with eyes.
S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27Take off immediately all contaminated clothing.
S28After contact with skin, wash immediately with plenty of..(to be specified by the manufacturer)
S29Do not empty into drains.
S30Never add water to this product.
S33Take precautionary measures against static discharges.
S34Avoid shock and friction.
S35This material and its container must be disposed of in a safe way.
S36Wear suitable protective clothing.
S37Wear suitable gloves.
S38In case of insufficient Ventilation wear suitable respiratory equipment.
S39Wear eye/face protection.
S40To clean the floor and all objects contaminated by this material use... (to be specified by the manufacturer).
S41In case of fire and/or explosion do not breathe fumes.
S42During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified).
S43In case of fire, use..(indicated in the space the precise type of fire fighting equipment. If water increases the risk, add-never use water).
S44If you feel unwell, seek, medical advice (show the label where possible).
S45In case of accident or if you feel unwell., seek medical advice immediately (show the label where possible)
S46If swallowed seek medical advice immediately and show this container or label
S47Keep at temperature no exceeding.. C (to be specified by the manufacturer)
S48Keep wetted with ... (appropriate material to be specified by the manufacturer)
S49Keep only in the original container.
S50Do not mix with .. (to be a specified by the manufacturer).
S51Use only in well ventilated areas.
S52Not recommended for interior use on large surface areas.
S53Avoid exposure - obtain special instructions before use instruction.
S54Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.
S55Treat using the best available techniques before discharge into drains or the aquatic environment.
S56Do not discharge into drains or the environment, dispose to an authorised waste collection point.
S57Use appropriate containment to avoid environmental contamination.
S58To be disposed of as hazardous waste.
S59Refer to manufacturer/supplier for information on recovery/recycling.
S60This material and/or its container must be disposed of as hazardous waste.
s 1/2 Keep locked up and out of reach of children.
s 3/7/9 Keep container tightly closed in a cool well-ventillated place.
s 3/9 Keep in a cool well-ventilated pace.
s 3/9/14 Keep in a cool, well-ventilated place away from ... (incompatible material to be indicated by the manufacturer)
s 3/914/49 Keep only in the original container in a cool wellventilated place away from ... (incompatible materials to be indicated by the manufacturer).
s 3/9/49 Keep only in the original container in a cool wellventilated place.
s 3/14 Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer).
s 7/8 Keep container tightly closed and dry.
s 7/9 Keep container tightly closed and in well-ventilated place.
s 20/21 When using do not eat, drink or smoke.
s 24/25 Avoid contact with skin and eyes.
s 36/37 Wear suitable protective clothing and gloves.
s 36/39 Wear suitable protective clothing and eye/face protection.
s 37/39 Wear suitable gloves and eye/face protection.
s 36/37/39 Wear suitable protective clothing, gloves and eye/face pro
s 47/49 Keep only in the original container at temperature not exceeding .. C (to be specified by the manufacturer).
F1Sensitive to air and humidity.
2Sensitive air and CO
3Hygroscopic
4Do not heat over ... C
5Dry material may explode.
6Reacts with acids.
7Keep under CO.
8Photosensitive.
9Keep under nitrogen.
10Keep under argon
11keep under inert gas.
12Shake before use
13Malodorous.
14Carefully observe warning label.
15Short shelf life.
16Decomposes easily.
17May decompose by explosion.
18Must be handled by instructed people only.
19Lachrymator.
20Not to be swallowed.
21Sensitive to humidity.
22Keep dust-free in the dark
23Sensitive to air.
24Spontaneously flammable with alcohol.
25Keep under CO.
26Before distillation test for absence of peroxides.
27Cool before opening.
28May become cloudy (Polyformaldehyde).
29Spontaneously flammable when dry.
30Sediment inavodiable.
31Do not puncture.
32Avoid contact with heavy metal salts esp. iron salts.
33Causes fall in blood pressure.
34Sensitive to CO.
Criteria EXPLOSIVE Precaution
Certain substances react exothermically thus generating gases. These may even explode on heating. Therefore storage is wet i.e. Under water or a suitable solvent. Avoid impact, Knocks, Sparks, Friction Fire & Heat.
Criteria OXIDISING Precaution
Certain substance mainly through oxygen evolution increase the fire hazard & the intensity of a fire. Avoid contact with flammable substances. Risk of ignition ! The substance promotes fire once started & impedes fire fighting.